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Excited to see this work published today in @J_A_C_S , fun chemistry and a real group effort here by @clairemcmullin , @Morales_Chem, @murcoswift and big Mike! (@BathChem)
pubs.acs.org/doi/10.1021/ja…
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Great to see this work out in @DaltonTrans , some lovely structures from back when Ollie was an MChem in the Hill group. Thanks as always to @clairemcmullin and Jacob for the calculations😊

pubs.rsc.org/dt/article/doi…
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Kyle Pearce retweeted
Triple bond formed between boron and oxygen! True oxoboranes have finally been synthesized. Check out Lukas and Christian's work, now online in @NatureChemistry
doi.org/10.1038/s41557…
Thanks to everyone for their contributions!
@SFBBoronPRO @ICBWuerzburg @Uni_WUE #chemtwitter
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Kyle Pearce retweeted
🎇 Excited to share this one: "A Nickel-Capped Calcium Hydride: Implications for Diene Hydrometallation" now posted on ChemRxiv: lnkd.in/gPAdBCGa Here, we report the synthesis and comprehensive characterization of a molecular complex featuring a σ–[Ca–H–Ni] interaction!
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Kyle Pearce retweeted
🧪 We’re hiring! 🚀

Interested in low-valent Group 13 & first-row transition-metal chemistry? Join us at TU Chemnitz for a postdoc position in our @ERC_Research CoG project #AGILE!

🔗 tu-chemnitz.de/verwaltung/per…

Please repost and spread the word! 📢

#ChemistryJobs #Postdoc
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Kyle Pearce retweeted
STRONTIUM POWER: Although this series follows the octet rule, only neutral Ph3N is stable. Ph3B is very resistant to double reduction. Only Ar3B.- radical anions are known. However, it had to surrender to strontium. @angew_chem doi.org/10.1002/anie.3…
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Kyle Pearce retweeted
A single-source precursor for mixed fuel gases!🔥Meet Mg[(CH₃)ZnH₃]—a hydride-rich organometallic that releases a mixture of #Hydrogen & #methane, at just 80 °C. A fundamental discovery that could open up practical applications! #energy #chemistry
doi.org/10.1126/sciadv…
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Kyle Pearce retweeted
We have an open 2-year research associate position in the group to work on heterometallic complexes and their applications in catalysis. Details here: jobs.ac.uk/job/DSZ858/res…
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Kyle Pearce retweeted
Another redox story with Ca/Zn system!
Our latest cooperative Ca/Zn venture: ether activation and alkyl migration. Some fun labelling experiments and stellar DFT by @Morales_Chem and @clairemcmullin disclosed within (@angew_chem).

onlinelibrary.wiley.com/doi/10.1002/an…
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Our latest cooperative Ca/Zn venture: ether activation and alkyl migration. Some fun labelling experiments and stellar DFT by @Morales_Chem and @clairemcmullin disclosed within (@angew_chem).

onlinelibrary.wiley.com/doi/10.1002/an…
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Kyle Pearce retweeted
📢 We’re hiring! The Stanford Chemistry Department is now actively conducting faculty searches (open area) - term to start on 9/1/2027:
- Assistant Professor in Chemistry
- Senior Faculty Position in Chemistry (Associate Professor or Professor)

Learn more: chemistry.stanford.edu/news/hiring-ch…
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Kyle Pearce retweeted
A couple of new pre-prints just out from the group.

If you're interested in main group chemistry or the mechanisms of photoredox catalysis at least one of these should be of interest!

chemrxiv.org/doi/abs/10.264…
chemrxiv.org/doi/abs/10.264…
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Kyle Pearce retweeted
Today we report on the mechanism of intermolecular deprotonation and decomposition of tin(II) amides, and highlight that this mechanism is thermally accessible for the well-known Sn(HMDS)2. Variation of the amide enables access to C(sp2)–H and C(sp3)–H activated products.
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Our latest paper investigating Calcium-Zinc cooperativity is just out in @Orgmet_ACS. Pleasure to see @MarcosLopezAg get stuck into this during his time at @BathChem, Vamos!
pubs.acs.org/doi/10.1021/ac…
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Kyle Pearce retweeted
Delighted to see that our latest contribution has been featured on the Front Cover of @green_rsc This recognition marks the last research article of the thesis of our brilliant PhD student @MarcosLopezAg A well-deserved reward! linkedin.com/showcase/susta…
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Kyle Pearce retweeted
Dat (@ng_tiendat) and Corinna's (@C_Czernetzki) joint study on ligand and metal specific outcomes of K reductions of flexible, extremely bulky NON-group 2 metal (inc. Be) complexes has appeared as a pre-print @ChemRxiv. tinyurl.com/y4t7srf4 #ozchem @AFOSR @arc_gov_au
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Kyle Pearce retweeted
Interested in the latest advances in main group metal redox catalysis?🔄

Now in @ChemEurope, covering key mechanistic concepts, recent breakthroughs, and future opportunities for sustainable catalysis.

⬇️ Check it out! ⬇️
…mistry-europe.onlinelibrary.wiley.com/doi/10.1002/ej…
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The heaviest Ae-Alumanyl (so far) just out in @DaltonTrans, check it out!

pubs.rsc.org/en/content/art…
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Kyle Pearce retweeted
Joe (@josephmparr) and co's work on using the normally inert NMR standard, TMS, as a ligand towards very Lewis acidic, neutral Ca and Sr complexes, has appeared as a pre-print @ChemRxiv. tinyurl.com/mr3sfccr.
See the Mg analogue here tinyurl.com/hv7refvy. #ozchem @AFOSR
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Kyle Pearce retweeted
Are you interested in main group metal redox catalysis?

🚨Check out our last preprint summarising recent developments in the area!

chemrxiv.org/doi/full/10.26…
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Kyle Pearce retweeted
🔥Hot Paper in @angew_chem!
Counterion control unlocks nucleophilic gallyl anions, enabling unsupported Ga–Au chemistry for NH₃ activation

Work led by @hellen_videa in our group, in collaboration with @TobiKraemer and @keelan542

@geqo_rseq @CIQSO_UHU
onlinelibrary.wiley.com/doi/10.1002/an…
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